{"id":1293,"date":"2013-10-30T22:20:47","date_gmt":"2013-10-30T13:20:47","guid":{"rendered":"https:\/\/seeds.web.nitech.ac.jp\/?p=1293"},"modified":"2020-02-05T16:15:13","modified_gmt":"2020-02-05T07:15:13","slug":"%e5%90%ab%e3%83%95%e3%83%83%e7%b4%a0%e3%83%95%e3%82%bf%e3%83%ad%e3%82%b7%e3%82%a2%e3%83%8b%e3%83%b3%e3%81%ae%e5%90%88%e6%88%90","status":"publish","type":"post","link":"https:\/\/seeds.web.nitech.ac.jp\/?p=1293","title":{"rendered":"\u542b\u30d5\u30c3\u7d20\u30d5\u30bf\u30ed\u30b7\u30a2\u30cb\u30f3\u306e\u5408\u6210"},"content":{"rendered":"

\uff5e\u30d5\u30c3\u7d20\u304c\u3064\u304f\u308b\u65b0\u3057\u3044\u6a5f\u80fd\u6027\u8272\u7d20\uff5e<\/strong><\/h4>\n

\u542b\u30d5\u30c3\u7d20\u30d5\u30bf\u30ed\u30b7\u30a2\u30cb\u30f3\u306e\u5408\u6210<\/h2>\n\n\n\n\n
\u7814\u7a76\u5206\u91ce\u5206\u985e\uff1a<\/strong>5302 \u5408\u6210\u5316\u5b66
\n\u7523\u696d\u5206\u985e\uff1a<\/strong>\u5316\u5b66\u5de5\u696d\uff0c\u5b66\u8853\u30fb\u958b\u767a\u7814\u7a76\u6a5f\u95a2<\/td>\n<\/tr>\n
\u30ad\u30fc\u30ef\u30fc\u30c9\uff1a<\/strong>\u6709\u6a5f\u5408\u6210\u5316\u5b66\uff0c\u6a5f\u80fd\u6750\u6599\uff0c\u30a8\u30cd\u30eb\u30ae\u30fc\u5909\u63db\uff0c\u6709\u6a5f\u30d5\u30c3\u7d20\u5316\u5b66<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n\n\n\n\n
\u5316\u5b66 <\/strong><\/td>\n<\/tr>\n
\u8907\u5408\u5316\u5b66<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n\n\n\n
\u67f4\u7530\u54f2\u7537\uff08\u672a\u6765\u6750\u6599\u5275\u6210\u5de5\u5b66\u5c02\u653b\uff09<\/strong><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n\n\n\n\n
\u7814\u7a76\u6982\u8981
\n<\/strong>\u3000\u30d5\u30bf\u30ed\u30b7\u30a2\u30cb\u30f3\u306f\u4eba\u4f53\u306b\u7121\u6bd2\u3067\u975e\u5e38\u306b\u5b89\u5b9a\u306a\u6709\u6a5f\u7269\u3067\u3042\u308a\u3001\u512a\u308c\u305f\u7269\u7406\u7684\u6027\u8cea\u3092\u6709\u3059\u308b\u3053\u3068\u304b\u3089\u3001\u6a5f\u80fd\u6027\u8272\u7d20\u3068\u3057\u3066\u6ce8\u76ee\u3055\u308c\u3066\u304d\u307e\u3057\u305f\u3002\u5f53\u7814\u7a76\u5ba4\u3067\u306f\u3001\u30d5\u30bf\u30ed\u30b7\u30a2\u30cb\u30f3\u306b\u30d5\u30c3\u7d20\u539f\u5b50\u3092\u5c0e\u5165\u3059\u308b\u3053\u3068\u306b\u3088\u308a\u5149\u5316\u5b66\u7684\u6027\u8cea\u307e\u305f\u306f\u7269\u7406\u7684\u6027\u8cea\u3092\u5236\u5fa1\u3057\u3001\u65b0\u898f\u306e\u6a5f\u80fd\u6027\u5206\u5b50\u6750\u6599\u306e\u8a2d\u8a08\u3068\u5408\u6210\u3092\u884c\u3063\u3066\u3044\u307e\u3059\u3002<\/td>\n		<\/td>\n\u7279\u5fb4
\n<\/strong>\u3000\u30d5\u30bf\u30ed\u30b7\u30a2\u30cb\u30f3\u306e\u30b9\u30bf\u30c3\u30ad\u30f3\u30b0\u306b\u3088\u308b\u51dd\u96c6\u3092\u9632\u3050\u305f\u3081\u3001\u5f53\u7814\u7a76\u5ba4\u3067\u306f\u3001\u3053\u308c\u307e\u3067\u306b\u30d5\u30c3\u7d20\u306e\u64a5\u6c34\u64a5\u6cb9\u6027\u3092\u5229\u7528\u3057\u305f\u975e\u51dd\u96c6\u6027\u30c8\u30ea\u30d5\u30eb\u30aa\u30ed\u30a8\u30c8\u30ad\u30b7\u5316\u30d5\u30bf\u30ed\u30b7\u30a2\u30cb\u30f3\u3092\u958b\u767a\u3057\u3066\u3044\u307e\u3059\u3002\u7279\u7b46\u3059\u3079\u304d\u306f\u3001\u3044\u304b\u306a\u308b\u6761\u4ef6\u4e0b\u3067\u3082\u5168\u304f\u51dd\u96c6\u6319\u52d5\u3092\u793a\u3055\u306a\u3044\u3068\u3044\u3046\u70b9\u3067\u3059\u3002<\/td>\n<\/tr>\n
\u80cc\u666f\u30fb\u5f93\u6765\u6280\u8853
\n<\/strong>\u3000\u30d5\u30bf\u30ed\u30b7\u30a2\u30cb\u30f3\u306f\u5206\u5b50\u9593\u76f8\u4e92\u4f5c\u7528\u306b\u3088\u308a\u51dd\u96c6\u3057\u3084\u3059\u3044\u3068\u3044\u3046\u6027\u8cea\u304c\u3042\u308a\u307e\u3059\u3002\u30d5\u30bf\u30ed\u30b7\u30a2\u30cb\u30f3\u306f\u51dd\u96c6\u4f53\u3092\u5f62\u6210\u3059\u308b\u3068\u3001\u30e2\u30ce\u30de\u30fc\u3067\u5f97\u3089\u308c\u3066\u3044\u305f\u96fb\u5b50\u7684\u306a\u69cb\u9020\u304c\u5909\u5316\u3057\u3001\u5149\u5b66\u7684\u306a\u5909\u6027\u3084\u89e6\u5a92\u4f5c\u7528\u306e\u5931\u6d3b\u304c\u898b\u3089\u308c\u307e\u3059\u3002\u975e\u51dd\u96c6\u4f53\u30d5\u30bf\u30ed\u30b7\u30a2\u30cb\u30f3\u3092\u5f97\u308b\u305f\u3081\u306b\u69d8\u3005\u306a\u5de5\u592b\u304c\u306a\u3055\u308c\u3066\u3044\u308b\u3082\u306e\u306e\u3001\u307b\u3068\u3093\u3069\u304c\u5d69\u9ad8\u3044\u7f6e\u63db\u57fa\u3092\u74b0\u306b\u5c0e\u5165\u3057\u3066\u300c\u7269\u7406\u7684\u306b\u300d\u51dd\u96c6\u3092\u9632\u3044\u3067\u3044\u307e\u3059\u3002<\/td>\n		<\/td>\n\u5b9f\u7528\u5316\u30a4\u30e1\u30fc\u30b8<\/strong>
\n\u3000\u89e6\u5a92\u3084\u5149\u5b66\u6750\u6599\u3001\u96fb\u8377\u767a\u751f\u5264\u306a\u3069\u306b\u5b9f\u7528\u5316\u3055\u308c\u3066\u304a\u308a\u3001\u3055\u3089\u306b\u306f\u300c\u5316\u5b66\u300d\u3068\u3044\u3046\u67a0\u7d44\u307f\u3092\u8d85\u3048\u3001\u5149\u7dda\u529b\u5b66\u7684\u6cbb\u7642\u85ac\u3084\u592a\u967d\u96fb\u6c60\u306a\u3069\u3078\u306e\u5fdc\u7528\u304c\u671f\u5f85\u3055\u308c\u3066\u3044\u307e\u3059\u3002<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u3000\"\"<\/a>
\n\u30c8\u30ea\u30d5\u30eb\u30aa\u30ed\u30a8\u30c8\u30ad\u30b7\u5316\u30d5\u30bf\u30ed\u30b7\u30a2\u30cb\u30f3\u306f\u64a5\u6c34\u64a5\u6cb9\u52b9\u679c\uff08fluorophobic repulsion\uff09\u306b\u3088\u308a\u6709\u6a5f\u5206\u5b50\u306f\u5168\u304f\u5bc4\u305b\u4ed8\u3051\u306a\u3044\u4e00\u65b9\u3001\u5206\u5b50\u5185\u306b\u304a\u3044\u3066\u306f\u30d5\u30eb\u30aa\u30ed\u57fa\u9593\u3067\u5206\u5b50\u306e\u5d69\u9ad8\u3055\u3092\u51cc\u99d5\u3057\u3066\u4e92\u3044\u306b\u8fd1\u3065\u3053\u3046\u3068\u3059\u308b\u6027\u8cea\uff08fluorophilic attraction\uff09\u3092\u3082\u3064\u3002<\/p>\n

\u4f01\u696d\u7b49\u3078\u306e\u63d0\u6848 <\/strong><\/span><\/p>\n

\u7814\u7a76\u8005\u304b\u3089\u4f01\u696d\u3078\u306e\u30e1\u30c3\u30bb\u30fc\u30b8<\/strong>
\n\u3000\u67f4\u7530\u7814\u7a76\u5ba4\u3067\u306f\u6709\u6a5f\u30d5\u30c3\u7d20\u5316\u5408\u7269\u306e\u5408\u6210\u306e\u7814\u7a76\u3092\u884c\u3063\u3066\u3044\u307e\u3059\u3002\u533b\u8fb2\u85ac\u54c1\u3084\u6a5f\u80fd\u6027\u6750\u6599(\u30d5\u30bf\u30ed\u30b7\u30a2\u30cb\u30f3)\u3001\u30b5\u30ea\u30c9\u30de\u30a4\u30c9\u306a\u3069\u5e45\u5e83\u304f\u7814\u7a76\u3092\u3057\u3066\u3044\u307e\u3059\u3002\u30d5\u30c3\u7d20\u306e\u3053\u3068\u3084\u30d5\u30c3\u7d20\u5316\u5408\u7269\u306b\u95a2\u3059\u308b\u3053\u3068\u306f\u4f55\u3067\u3082\u3054\u76f8\u8ac7\u304f\u3060\u3055\u3044\u3002<\/p>\n

\u6587\u732e\u30fb\u7279\u8a31<\/strong>
\n\u30fbYoshiyama, H.; Shibata, N.; Sato, T.; Nakamura, S.; Toru, T. Chem. Commun., 2008, 1977.
\n\u30fbYoshiyama, H.; Shibata, N.; Sato, T.; Nakamura, S.; Toru, T. Org. Biomol. Chem. 2009, 7, 2265.
\n\u30fbDas, B.; Umeda, M.; Tokunaga, E.; Toru, T.; Shibata, N. Chem. Lett. 2010, 39, 337.
\n\u30fbReddy, M., R.; Shibata, N.; Kondo, Y.; Nakamura, N. Toru, T. Angew. Chem. Int. Ed. 2006, 45, 8163.
\n\u30fbYoshiyama, H.; Shibata, N.; Sato, T.; Nakamura, S.; Toru, T. Org. Biomol. Chem., 2008, 6, 4498.<\/p>\n\n\n\n
\u8a66\u4f5c\u54c1\u72b6\u6cc1<\/strong><\/td>\n\u7121\u3057<\/td>\n\u63b2\u793a\u53ef<\/td>\n\u63d0\u4f9b\u53ef<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

 <\/p>\n\n\n\n
\u5229\u7528\u53ef\u80fd\u306a\u8a2d\u5099\u30fb\u88c5\u7f6e<\/strong>
\nNMR
\nHPLC
\nLCMS
\nGC
\nIR<\/td>\n		\u5171\u540c\u7814\u7a76\u3092\u5e0c\u671b\u3059\u308b\u30c6\u30fc\u30de
\n<\/strong>\u533b\u8fb2\u85ac\u4e2d\u9593\u4f53\u306e\u5408\u6210\u6cd5\u306e\u958b\u767a
\n\u5408\u6210\u30d7\u30ed\u30bb\u30b9\u306e\u958b\u767a
\n\u65b0\u898f\u533b\u85ac\u54c1\u5019\u88dc\u5316\u5408\u7269\u306e\u5408\u6210
\n\u6a5f\u80fd\u6027\u6750\u6599\u306e\u958b\u767a
\n\u74b0\u5883\u306b\u3084\u3055\u3057\u3044\u5408\u6210\u6cd5\u306e\u958b\u767a
\n\u4e0d\u6589\u5408\u6210\u6cd5\u306e\u958b\u767a<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n\n\n\n
\u7814\u7a76\u8005\u30c7\u30fc\u30bf\u30d9\u30fc\u30b9\u3068\u306e\u30ea\u30f3\u30af<\/strong>\uff08\u540d\u524d\u3092\u30af\u30ea\u30c3\u30af\u3057\u3066\u304f\u3060\u3055\u3044\uff09
\n\u7814\u7a76\u8005\u540d\uff1a\u67f4\u7530\u54f2\u7537<\/a><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n\n\n\n
\uff30\uff24\uff26\u8868\u793a\u3068\u5370\u5237<\/a><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n","protected":false},"excerpt":{"rendered":"

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